Фторопласт

28 июля 2015г. - 19:10 8612 просмотров


ФторопластГруппу фторсодержащих полимеров получаемых путем полимеризации тетрафторэтилена принято называть фторопласт. Этот полимер обладает просто уникальными качествами. Связь атомов углерода и фтора, в этой специфической структуре молекул, чрезвычайно сильна, что и определяет такой неповторимый набор физических и химических характеристик фторопластов, сочетание которых не встречаются ни в каких других материалах.

Фторопласты имеют чрезвычайно высокую устойчивость к воздействию химических сред. Обладают неплохими прочностными, отличными антифрикционными, диэлектрическими и анти адгезионными  параметрами, и имеют способность не терять эти свойства в большом температурном  диапазоне.

Для улучшения нужных параметров полимеров, таких как, износостойкость, твердость, стойкость к деформации, теплопроводности, уменьшения коэффициента трения, в полимеры добавляют различные наполнители. Такие модифицированные фторопласты применяются во многих областях быта, строительства, промышленности и сельского хозяйства.

Области применения

Особые свойства фторопласта, их уникальное сочетание обуславливает сферы его применения и использования. К этим свойствам относится: стойкость к атмосферным и химическим воздействиям, замечательные антифрикционные и уплотнительные свойства, отличные анти адгезионные и превосходные диэлектрические и электрические свойства, высокая термостойкость и абсолютная инертность к пищевым и биологическим средам.


Все фторопластовые изделия гигиенически сертифицированы

Фторсодержащие полимеры благодаря своим уникальным свойствам стали незаменимыми для электротехнической, химической, радиоэлектронной промышленности, машиностроения, производства кабельной продукции и проводов, авиастроении и приборостроении, автомобилестроении, энергетической и атомной промышленности. В производстве, применение фторопласта, модифицированного различными наполнителями, наиболее часто наблюдается в изготовлении:

  • узлов трения, выполняющих роль подшипников скольжения;
  • уплотнительных систем в виде уплотнительных колец, манжет, как прокладки из фторопласта, для механических и гидравлических устройств, а также плунжерных и поршневых компрессоров;
  • направляющих конструкций для перерабатывающего пищевые продукты оборудования, для загрузочных автоматов и сборочных конвейеров;
  • опор скольжения в конструкциях железнодорожных и автомобильных мостов;
  • направляющих для тросов строительных и промышленных механизмов;
  •  различных систем управления, систем реверсивных устройств, систем нейтрализации газа и жидкостей;
  • протезов кровеносных и сердечных сосудов, емкостей для хранения крови и других изделий в медицинской отрасли.

Возможно вы, являетесь производителем вышеперечисленных изделий, а возможно покупателем, ищущим эти изделия, тогда на нашем сайте, воспользовавшись соответствующими каталогами, вы сможете помочь друг другу. Подав, на страницах нашего сайта объявление, о своих предложениях, вы многократно увеличиваете вероятность отклика на ваш призыв.

Изделия из фторопласта
Детали и изделия из фторопласта, а также композиций на его основе, широко применяются в химической аппаратуре в виде: емкостей, диафрагм, мембран, клапанов, трубопроводов, уплотнительных устройств и прокладок, колонн, лент для транспортеров.

Чрезвычайно высокая стойкость к химическому воздействию, позволяет фторопластовым изделиям длительно противостоять воздействию солнечной радиации, морского тумана, плесневых грибков.

Нейтральность по отношению к органическим и неорганическим реагентам настолько высока, что даже, не имеется методов, для испытания на стойкость в таких средах. Высокая стойкость к радиации, позволяет применять фторопласт, для изолирования проводов оборудования атомных электростанций.

Провода во фторопластовой изоляции, можно применять как нагреватели, непосредственно работающие в растворах щелочей и кислот. Им не страшны протекания керосина, масла, гидравлических жидкостей, повышенные температуры, поэтому нашли широкое применение в качестве бортовых кабелей самолетов. Неоспоримо их преимущество при эксплуатации в условиях разреженной атмосферы, где теплоотводящие возможности уменьшены.

Физические свойства и технические характеристики фторопласта поистине уникальны.

Диэлектрическая проницаемость фторопласта практически не зависима от температуры, что сказывается на его фаз стабильности, то есть, электрическая длина не измена в большом температурно частотном диапазоне. Поэтому, он используется в РЭА, работающих с фазово-импульсной модуляцией, в измерительных фаз чувствительных устройствах и РЛС.

Негорючесть фторопласта, еще одно его положительное качество, загораться он способен только в кислороде, чем сильно отличается от полиэтилена, при этом теплота сгорания в десять раз меньшая, чем у полиэтилена. При горении он не плавится, а только обугливается. В дыме содержится фтор фосген, который ядовит, поэтому надо учитывать то, что при нагреве выше 773˚К начинают выделяться опасные газы. Фторопласт не поддерживает горение, и при удалении его из открытого пламени, его горение прекращается. Фторопласт при его нагревании в вакууме не склонен к выделению газообразных составляющих, поэтому его хорошо использовать в качестве подложки в ГИС на тонких пленках. Все эти незаурядные качества фторопласта, свидетельствуют о том, насколько он уникален, и том, что у полимеров большие перспективы в будущем.

Но у фторопласта есть и недостатки. Из-за своей химической инертности он пассивен адгезионно, то есть, практически не поддается склеиванию. Однако уже найдены способы преодоления этого недостатка, при помощи обработки расплавами окислителей при температуре свыше 370 ˚К или плазмой тлеющего разряда в среде кислорода. Таким образом, изготавливаются фторопластовые фольгированные пленки, а также пленки, имеющие одну липкую сторону.

Как видно из табличных данных, плотность фторопласта находится в промежутке 2,17- 2,28 г/см3

 

Технические характеристики фторопласта

Такая характеристика,  как температура плавления фторопласта 327  °С, взаимосвязана с тем, что при увеличении температуры он не переходит в состояние вязко текучести. Поэтому, он не перерабатывается в экструдерах, из-за еще высокой вязкости при 350 °С, находящейся в пределах 1010 Па-с.  Вследствие этого пленку приходится готовить с помощью более дорогого метода, ее изготавливают на прецизионных токарных станках способом строжки.

Еще один из недостатков фторопласта заключается в том, что под нагрузкой он плохо работает, и обладает ползучестью. Поэтому приходится улучшать его механические свойства, прибегая к модифицированию радиационным воздействием и армированию стекловолокном.

Для производства заготовок типа фторопласт пластины, фторопласт стержни, фторопласт круг,  применяется способ холодной прессовки и дальнейшего спекания, при этом используется  термически обработанный, гранулированный  ф4 фторопласт гост 1007-80 марок ПН и О. Прессование производится на прессах с гидравлическим приводом, работающих с давлением 350 кгс/см2.

Более качественные заготовки получаются при двустороннем прессовании. Спекание происходит при температуре 370-385 °С и длится в течение нескольких суток. Длительность этого процесса зависит от массы спекаемых заготовок. Если спекание производится с температурой выше 385 °С, механическая прочность заготовки снижается, если ниже 370 °С увеличивается продолжительность спекания. Условия прессования и дальнейшего спекания напрямую зависят от того, какой полимер при этом применяется, и каковы габариты заготовки.


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